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 Metalurgia

INTERNATIONAL

(magazine set-up in 1995)

 

English version, published by

romanian metallurgical foundation

 

Honorary president of  scientific publishing house f.m.r.

Dr. ec. Lepădatu v. gheorghe

                       

 
                                                        vol. XI

                                                                  (2006)

                                                                  no.7

 

romanian metallurgical foundation

Scientific publishing house

Honourary Staff

(in alphabetical order)

 

bensabra    hakim    (algeria),    chabour    salem    (algeria),     gencang    yang    (china),    R.  S.     HOUK     (S.U.A.),

I. IMRIŠ  (TECHNICAL  UNIVERSITY  OF  KOŠICE,  SLOVAK  REPUBLIC),      pușici miho (Slovenia), roșescu     gheorghe  (grecia),     roxana  ruxandra     (california),   w.m. nicola (tri. state university angola, indiana, s.u.a.), xianqing you (china)

 

 

romanian metallurgical foundation

Scientific publishing house

 

editorial  board :

 

Prof. colan horia Ph. D., member of Romanian Academy of Technical    Sciences

Prof. Coșmeleață georgeta Ph. D.

Prof. Dumitrescu Constantin Ph. D., deputy member of Romanian Academy of Technical Science

Prof. French David Ph. D., CSIRO Energy Technology, Australia

Prof. Gălușcă Dan-Gelu Ph. D.

Prof. Mihaela Grigore Ph. D., University of New South Wales, Sydney, Australia

Prof. Lawson Cristopher Ph. D., Copenhague Technical Institute, Denmark

Prof. Nicolae Avram Ph. D.

Prof. Maria Nicolae Ph. D.

Prof. doc. Oprea Florea Ph. D., member of Romanian Academy of Technical Sciences

Prof. Veena Sahajwalla Ph. D., University of New South Wales, Sydney, Australia

Prof. Sakurovs Richard Ph. D., CSIRO Energy Technology, Australia

Prof. Salvo Luc Ph. D., Grenoble National Politechnical Institute, France

Prof. Saiter Jean-Marc Ph. D., Rouen University, France

Prof. Scorțea Costin Ph. D.

Prof. Simiti Ioan Vida Ph. D.

Prof. Sofroni Laurenție Ph. D., member of Romanian Academy of Technical Sciences

Prof.  Șaban Rami Ph. D

Prof. ȘTEFĂNESCU DORU Ph. D, Ohio State University   Columbus, S.U.A.

 

advisory board :

 

Prof.  bejan Mircea Ph. D

Prof.  cănănău nicolae  Ph. D

Prof.  hepuț teodor Ph. D

Prof.  TODERIȚA NEMEȘ Ph. D

Prof.  Doina Răducanu Ph. D

Prof.  Ripoșan Iulian Ph. D

Prof.  samoilă Corneliu  Ph. D

Prof.  SOFONEA GALAgTION Ph. D

 

Managing Director:

Editor-in-chief:

Professor Scorțea Costin Ph. D.

 

Manager Scientific Publishing House F.M.R.:

eng. Florentina Brândușa Scorțea

 

 

Contents

 

Issn 1582 – 2214

 

Rodica-Mariana Ion, OLIVEIRA A. S., FERREIRA Vieira L. F.:  New hibrid materials (microcrystalline

 cellulose – porphyrin/phthalocyanine) for water

 depollution ……………………………………...…. 5

 

GEAMĂN  Virgil, JIMAN Vasile: Evaluation of

 densification mechanism during plastic yielding

 and diffusion by hot isostatic pressing ………..... 13

 

CALEA G. Gheorghe, GHIMIȘ D., PAUN C.,  PAUN S., NICOLAE Avram: Studies regarding the increase of

the availability of some components of the machines

by using the functional ceramic coating …….….. 16

 

Ciobanu Ioan, Monescu Vlad, Mașniță Mihai:

A study regarding the influence of the pouring

temperature over a casting solidification from

an eutectic grey cast iron ………………………... 21

 

GHIMBĂȘEANU      Ioan:   Statical   analysis  of  a

test-tube …………………………………………... 28

 

BATALU Dan, Georgeta Coșmeleață, ALOMAN Angel, Ciucă I., GUOQIU He, XIAOSHAN Liu,

 ZHIHUA Zhang: Critical analysis of some

Experimental   Ti-Ni   phase diagrams. Short

review …………………………………………...… 32

 

Elena Drăgulănescu: About management for

design ……………………………………………... 40

 

? FOSECO Turbostop system – reference list …I-II

? Press release ……………..…..……........... III – VI

? New books, published by romanian metallurgical

foundation……………….……..……..... VII - VIII

abstract

metalurgia International 7/2006

 

D.C.: 669.2/.8

Key words: porphyrins, microcrystalline cellulose, o-nitrophenol, photodegradation

Rodica-Mariana Ion, OLIVEIRA A. S., FERREIRA Vieira L. F.:  New hibrid materials (microcrystalline cellulose – porphyrin/phthalocyanine) for water depollution

Metalurgia International (vol. XI), no.7, 2006, p. 5

The photochemical degradation processes are generally based on oxidative reactions initiated by very reactive radicals, such as OH. radicals. However, there are a number of refractory substances (nitrophenols being one of them) that degrades very slowly under these conditions. The heterogeneous photocatalysts seems to be one of the most efficient ways to destroy aquatic phenolic pollutants. In this paper were developed  new types of heterogeneous photocatalysts that destroy and detoxifies waste water streams containing up to 300 ppm of 2 - nitrophenol pollutants. The adsorption of zinc-complexes of 5,10,15,20 - p - sulphonato - phenyl - porphyrin (ZnTSPP)    and   4,8,18,22 - tetra -   sulphonato   -  phthalocyanine   (ZnTSPc)   on microcrystalline cellulose occurs after swelling the matrix with a polar protic solvent, by entrapment of the probes within the polymer chains, for low loadings, and in “pools” of microcrystals, for high loadings. The adsorbed compounds were characterised by ground-state diffuse reflectance technique (GSDR). These adsorbed complexes have also been studied as catalysts for o-nitrophenol photochemical degradation in aqueous solution.

                         By adsorption on microcrystalline cellulose the degree of photodestruction of such complexes of ZnTSPP and ZnTSPc is smaller in comparison to that in homogeneous phase due to a longer diffusion time toward the photoactive molecules.

 

D.C.: 669.2

Key words: HIP, compression mechanism, full density

GEAMĂN  Virgil, JIMAN Vasile: Evaluation of densification mechanism during plastic yielding and diffusion by hot isostatic pressing

Metalurgia International (vol. XI), no.7, 2006, p. 13

Hot isostatic processing (HIP), involves the simultaneous application of pressure and elevated temperature to materials. Under these conditions of heat and pressure, internal pores or defects within a solid body or a powder compact collapse and weld up. HIP is today used for a lot of applications, like upgrading castings (removing shrinkage pores in interdendritic space), densifying pre-sintered components, consolidation of powders and interfacial bonding.

The main densification  mechanisms  during  hot  isostatic  pressing are:  plastic yielding, power law creep, densification by diffusion and Nabarro-Herring and Coble creep.

The paper presents some theoretical data for calculating densification mechanisms during plastic yielding and diffusion.

 

D.C.: 574

CALEA G. Gheorghe, GHIMIȘ D., PAUN C.,  PAUN S., NICOLAE Avram: Studies regarding the increase of the availability of some components of the machines by using the functional ceramic coating

Metalurgia International (vol. XI), no.7, 2006, p. 16

This paper presents the ceramic (Al2O3) coating technology (Al2O3) under plasma jet applied to spindles used in construction systems.

 

D.C.: 621.746.628

Ciobanu Ioan, Monescu Vlad, Mașniță Mihai: A study regarding the influence of the pouring temperature over a casting solidification from an eutectic grey cast iron

Metalurgia International (vol. XI), no.7, 2006, p. 21

This paper presents the results of a research made by the authors regarding the influence of the pouring temperature over solidification kinetics. It was used a 2D mathematical model for the

solidification simulation. It was analysed a cast bar with section 20 x 150mm poured from an eutectic grey cast iron. The overheat at pouring above liquidus temperature was between 0 ˚C and 250 ˚C. We did some observation regarding the overheat influence over the solidification time and temperature field from casting and from the mould.

 

D.C.: 621.315.592

GHIMBĂȘEANU Ioan: Statical analysis of a test-tube

Metalurgia International (vol. XI), no.7, 2006, p. 28

The paper presents the algorithm of finite element analysis of the steel test tube tensile test in order to determine the usual mechanical characteristics assisted by the computer. This finite element analysis of a test tube tensile test is made through CATIA graphic programme.

 

D.C.: 620.193.

Key words: Ti-Ni binary phase diagram, critical analysis, shape memory alloy

BATALU Dan, Georgeta Coșmeleață, ALOMAN Angel, Ciucă I., GUOQIU He, XIAOSHAN Liu, ZHIHUA Zhang: Critical analysis of some experimental Ti-Ni phase diagrams. Short review

Metalurgia International (vol. XI), no.7, 2006, p. 32

TiNi shape memory alloys have a wide area of applications in various fields. The alloys are used in the medical engineering for producing smart devices, such as stents or self fixing implants, dental implants etc.

    The authors analysed three of the most cited binary Ti-Ni phase diagrams and two partial phase diagrams that concern the homogeneity domain of TiNi compound.

                        Ti-Ni binary phase diagram is one of the most important diagrams of Ti based binary alloys, such as Ti-Al and Ti-Fe. The importance of Ti-Ni phase diagram is mainly due to the TiNi shape memory alloy with its special characteristics.

    In the present paper the authors suggested a schema of the binary Ti-Ni phase diagram and established its corresponding flow diagram.

                        The results are important for pointing out a reliable binary Ti-Ni phase diagram and for indicating new directions of research of Ti-Ni alloys, in order to clarify the related controversies.

 

D.C.: 621.762.4; 66.046.562

Elena Drăgulănescu: About management for design

Metalurgia International (vol. XI), no.7, 2006, p. 40

In the technical field management must be applied like a for design like a process and that process must belong to an organization which is very good lead. This modern text is designed to prepare you for  your future vision about management in the design for technical field.

While ideas, theories, techniques, and data are dynamic, the information contained in this work will provide you a quick and useful reference as well as a guide for future understanding for many years to come, about management in design.

Are offered some ideas about intelligence information, organizational communications and the function of a decision support system.

General  Principles  and  Functions  of Management are need for modern, technical “Design”.

In metallurgic industry and processing industry the knowledges about management in design, about the principles of management serve as guides for  managers who engage in carrying out specific functions to solve problems and make decisions.

This is a very large area of knowledges.

The first step in management in design is to develop a clear understanding of the various information flows that must be dealt with. Software helps always this process. Is very important to apply a decision support system and to know about the your managerial functions of planning, organizing, leading and controlling.

 

 

1.         The “METALURGIA INTERNATIONAL” magazine receives manuscripts of papers including basic  scientific research and industrial  research in the following fields: metallurgy, materials science and engineering and different relating processes.

2.         Original papers not previously publishing  in any other journal, or not sent for publishing before, are accepted.

3.         After publication, the copyright is transferred to the publishing house.

4.         Every manuscript will be referred, their reports form the basis of the Editor’s decision.

5.         The manuscripts sent to the Editor  will not returned to the author, even  they are not published.

6.         The manuscripts will be sent to the following address:

METALURGIA INTERNATIONAL

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REDACTION

Copyright © 2006 The f.m.r. scientific publishing house, accredited by

the romanian council for universitary research